Pressure-induced structural disordering and anomalous pressure-volume behaviour in high-entropy zirconates

TL;DR

This study investigates how high pressure affects the structure of high-entropy zirconates with different particle sizes, revealing phase stability, disordering, and anomalous pressure-volume behavior linked to polyhedral distortions.

Contribution

It provides new insights into the pressure-induced structural disordering and anomalous P-V behavior in high-entropy zirconates with varying particle sizes.

Findings

Smaller particles exhibit pure defect-fluorite phase.

Larger particles show mixed phases with increasing pyrochlore content.

Anomalous pressure-volume behavior occurs between 7-15 GPa, decreasing with particle size.

Abstract

The ambient-temperature high-pressure behaviour of (La0.2Nd0.2Sm0.2Gd0.2Yb0.2)2Zr2O7 zirconate (HEZ) nanopowders with three different average particle sizes (~25nm, ~45 nm and ~ 68nm) were studied using synchrotron X-ray diffraction (SR-XRD) measurements up to ~30 GPa. Smaller particle-size HEZ nanopowder (~25 nm), synthesized at the lower sintering temperature, exhibits pure defect-fluorite (DF) phase, whereas larger particle-size HEZ nanopowders (~45nm and ~68nm), synthesized at the higher sintering temperature, exhibit mixture of DF and pyrochlore phase (PY). The phase fraction of the PY phase increases with sintering temperature and hence with the particle size. All the HEZ nanopowders exhibit stability of initial structures (DF and PY) up to ~ 30 GPa, though phase fraction of PY phase in larger particle-size HEZ nanopowders successively reduces with pressure which is concomitant with significant variation in ox48f fractional coordinate in PY phase. Both the phases in all the studied samples exhibit anomalous pressure-volume (P-V) behaviour between ~7 to 15 GPa. The anomaly decreases with increasing particle size of HEZ nanopowders. The variation of bond lengths and polyhedron volume with pressure suggests that the anomalous P-V behaviour and structural changes at high pressures are primarily due to the distortion of the polyhedrons in DF and PY structures in HEZ nanopowders.