Image-based measurements of Tafel slopes in aqueous MV/4-HO-TEMPO Flow Batteries

TL;DR

This paper introduces a novel image-based method to directly measure Tafel slopes and electrochemical kinetics in aqueous redox flow batteries, simplifying experiments and providing valuable data for system optimization.

Contribution

It presents a new spectroelectrochemical imaging approach to measure Tafel kinetics and charge transfer resistances without reference electrodes in flow batteries.

Findings

First direct measurement of Tafel slopes in this type of RFB

Method reduces experimental complexity and uncertainty

Provides quantitative data for charge transfer and kinetics

Abstract

A total organic aqueous redox flow battery (RFB) employing methyl viologen (MV) electrolyte and 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (4-HO-TEMPO) is tested and characterized under microfluidic conditions. The absence of physical membrane and the quasi-two-dimensional energy transfers occurring in this RFB design enables the first direct measurement of Tafel kinetics, charge transfer, and charge transport resistances for both anolyte and catholyte reactants during the RFB operations. The methodology reported in this work combines spectroelectrochemical imaging and analytical modeling of the periodic mass and charge transfer equations. The Tafel kinetics and charge transfers resistances are measured through several RFB geometries and operating conditions without the need of reference electrode nor absorptivity coefficient calibration, which simplifies the experimental setup, eases the measurements and suppresses the uncertainty related to the electrolyte potential value. Data provided in this work (concentration fields, kinetics properties, electrochemical impedances) quantify the charge transfer in these systems and can serve as reference values for further advanced RFB numerical simulations and design optimization.