Line and Planar Defects with Zero Formation Free Energy: Applications of the Phase Rule toward Ripening-Immune Microstructures

TL;DR

This paper explores conditions allowing extended defects in crystalline materials to have zero formation free energy at thermodynamic ground state, using the phase rule to predict defect coexistence and microstructure stability.

Contribution

It introduces a thermodynamic framework treating extended defects as phases, revealing conditions for defect stability and ripening-immune microstructures.

Findings

Extended defects can have zero formation free energy at ground state.

The generalized phase rule limits defect types coexisting in equilibrium.

Microstructures can be designed to be immune to coarsening.

Abstract

Extended one- and two-dimensional defects in crystalline materials are usually metastable. The thermodynamic ground state of the material is presumed to be defect-free. Here, we investigate the conditions under which extended defects, such as grain boundaries, can exist in a multicomponent alloy when the latter reaches the thermodynamic ground state allowed by the Gibbs phase rule. We treat all extended defects as low-dimensional phases on the same footing as the conventional bulk phases. Thermodynamic analysis shows that, in the ground state, the formation free energies of all extended defects must be zero, and the system must follow a generalized phase rule. The latter predicts that only a finite number of symmetry-related defect types can coexist in the material in the ground state. Guided by the phase rule, we discuss finite-size polycrystalline and/or polyphase microstructures that are fully immune to coarsening and their possible transformations.