Interfacial Effects Determine Nonequilibrium Phase Behaviors in Chemically Driven Fluids

TL;DR

This paper investigates how interfacial effects influence nonequilibrium phase behaviors in chemically driven fluids, revealing the importance of interface properties in phase separation under nonequilibrium conditions.

Contribution

The study develops a first-principles theory and uses microscopic simulations to predict nonequilibrium coexistence and flux localization in chemically driven fluids.

Findings

Mesoscopic fluxes depend on nonequilibrium fluctuations at interfaces.

Theoretical predictions match simulation results for phase coexistence.

Interfacial properties are central to nonequilibrium condensation phenomena.

Abstract

Coupling between chemical fuel consumption and phase separation can lead to condensation at a nonequilibrium steady state, resulting in phase behaviors that are not described by equilibrium thermodynamics. Theoretical models of such "chemically driven fluids" typically invoke near-equilibrium approximations at small length scales. However, because dissipation occurs due to both molecular-scale chemical reactions and mesoscale diffusive transport, it has remained unclear which properties of phase-separated reaction-diffusion systems can be assumed to be at an effective equilibrium. Here we use microscopic simulations to show that mesoscopic fluxes are dependent on nonequilibrium fluctuations at phase-separated interfaces. We further develop a first-principles theory to predict nonequilibrium coexistence curves, localization of mesoscopic fluxes near phase-separated interfaces, and droplet size-scaling relations in good agreement with simulations. Our findings highlight the central role of interfacial properties in governing nonequilibrium condensation and have broad implications for droplet nucleation, coarsening, and size control in chemically driven fluids.