Strain-Gradient and Curvature-Induced Changes in Domain Morphology of BaTiO3 Nanorods: Experimental and Theoretical Studies

TL;DR

This study combines experimental and theoretical approaches to understand how OH- ions influence lattice strain, growth, and domain morphology in BaTiO3 nanorods, revealing curvature-induced domain stripe formation.

Contribution

It provides new insights into how internal chemical strains and curvature affect domain structures and growth in BaTiO3 nanorods, with potential applications in flexible electronics.

Findings

OH- ions induce lattice elongation along the c-axis.

Curvature exceeding a critical angle causes domain stripe formation.

Internal chemical strains are key in nanorod growth and morphology.

Abstract

We investigate the impact of OH- ions incorporation on the lattice strain and spontaneous polarization of BaTiO3 nanorods synthesized under different conditions. It was confirmed that the lattice strain depends directly on Ba supersaturation, with higher supersaturation leading to an increase in the lattice strain. However, it was shown that crystal growth and observed lattice distortion are not primarily influenced by external strain; rather, OH- ions incorporation plays a key role in generating internal chemical strains and driving these processes. By using the less reactive TiO2 precursor instead of TiOCl2 and controlling Ba supersaturation, the slower nucleation rate enables more effective regulation of OH- ions incorporation and crystal growth. This in turn effects both particle size and lattice distortion, leading to c/a ratio of 1.013 - 1.014. The incorporation of OH- ions induces lattice elongation along the c-axis, contributing to anisotropic growth, increasing of the rod diameter and their growth-induced bending. However, the possibility of the curvature-induced changes in domain morphology of BaTiO3 nanorods remains almost unexplored. To study the possibility, we perform analytical calculations and finite element modeling, which provide insights into the curvature-induced changes in the strain-gradient, polarization distribution, and domain morphology in BaTiO3 nanorods. Theoretical results reveal the appearance of the domain stripes in BaTiO3 nanorod when the curvature exceeds a critical angle. The physical origin of the domain stripes emergence is the tendency to minimize its elastic energy of the nanorod by the domain splitting. These findings suggest that BaTiO3 nanorods, with curvature-controllable amount of domain stripes, could serve as flexible race-track memory elements for flexo-tronics and domain-wall electronics.