The meaning of Li diffusion in cathode materials for the cycling of Li-ion batteries: A case study on LiNi0.33Mn0.33Co0.33O2 thin films

TL;DR

This study investigates Li diffusion in LiNi0.33Mn0.33Co0.33O2 thin film cathodes, revealing that diffusion controls capacity and rate capability, with diffusivities being largely independent of potential, SOC, and cycle number.

Contribution

It provides a comprehensive analysis of Li diffusion mechanisms in thin film cathodes using multiple measurement techniques, establishing diffusion as the key factor in capacity and rate performance.

Findings

Capacity is diffusion-limited at higher C-rates.

Diffusivities are consistent across potential, SOC, and cycle number.

A C-rate limit of 0.01C for full delithiation was identified.

Abstract

We demonstrate that for polycrystalline LiNi0.33Mn0.33Co0.33O2 c-axis textured thin film cathodes of rechargeable lithium-ion batteries, the kinetics of Li storage and release including maximum specific capacity is determined by Li diffusion. The C-rate capability and long-term cycling behavior were investigated. The films exhibited up to 30% of the expected practical capacity even at low C-rates. However, 100% capacity was achieved at very low cycling rates below 0.01C. The capacity showed a reversible behaviour with changing current density, indicating no film degradation. The C-rate capability experiment showed a square root dependence of capacities on current density, which corresponds to a diffusion-controlled process. The estimated diffusivities from the cycling experiments are independent of the current density. The Li chemical and tracer diffusivities were measured using standard electrochemical and non-electrochemical diffusion measurement techniques. Chemical diffusivities, thermodynamic factor, and hence Li tracer diffusivities were determined from potentiostatic intermittent titration (PITT) and electrochemical impedance spectroscopy (EIS) experiments as a function of electrode potential and state of charge (SOC). The diffusivities were found to be approximately independent of potential, SOC and cycle number. The Li tracer diffusivities were validated by 6Li tracer diffusion experiments with secondary ion mass spectrometry (SIMS). The diffusivities obtained by PITT and SIMS were found to be more reliable for Li uptake and release than those obtained by EIS. Based on the diffusion results, a C-rate limit for full film delithiation below 0.01 C was calculated due to slow Li diffusion.