Counting observables in stochastic excursions

TL;DR

This paper develops a framework to analyze the full statistical distribution of counting observables during stochastic excursions in non-equilibrium processes, revealing fundamental relations, fluctuation theorems, and thermodynamic bounds at the single-excursion level.

Contribution

It introduces a novel analytical approach to characterize counting observables in stochastic excursions, linking fluctuations to steady state noise and uncovering new fluctuation relations.

Findings

Derived explicit distributions for counting observables and excursion durations.

Discovered a fundamental relation between excursion-level fluctuations and steady state noise.

Established a fluctuation theorem and thermodynamic uncertainty relation for individual excursions.

Abstract

Understanding fluctuations of observables across stochastic trajectories is essential for various fields of research, from quantum thermal machines to biological motors. We introduce a framework to analyze the statistics of counting observables in sub-trajectories$-$dubbed as stochastic excursions$-$of processes out of equilibrium. Given a partition of the state space into two sets $A$ and $B$, an excursion is defined as the segment of the trajectory that starts with a transition from $A$ to $B$ and ends upon the first return from $B$ to $A$. Our approach offers analytical expressions for the full distribution of counting observables (such as currents, heat, work, entropy production, and dynamical activity) and the excursion duration, capturing their correlations and finite-time fluctuations. As our main result, we uncover a nontrivial fundamental relation between fluctuations of counting observables at the single-excursion level and the steady state noise obtained from full counting statistics, offering a tool to inspect noise sources. We also show the existence of a fluctuation theorem and a thermodynamic uncertainty relation at the level of individual excursions. We discuss examples from distinct fields in which the excursion framework naturally addresses relevant questions, and explore in more detail how analyzing excursions yields additional insights into the operation of the three-qubit absorption refrigerator.