Partitioning Law of Polymer Chains into Flexible Polymer Networks

TL;DR

This study uncovers a universal law governing how linear polymer chains distribute within flexible polymer networks, based on their size and network mesh, using a novel contactless measurement method.

Contribution

The paper introduces a new universal law for polymer partitioning into networks and a contactless method to measure partition ratios experimentally.

Findings

Partition constant depends on $(R_g / l_ ext{cycle})^2$

Universal law applies across different network structures

New label-free measurement technique developed

Abstract

The equilibrium partitioning of linear polymer chains into flexible polymer networks is governed by intricate entropic constraints arising from configurational degrees of freedom of both chains and network, yet a quantitative understanding remains elusive. Using model hydrogels with precisely defined network structures, we experimentally reveal a universal law governing linear polymer partitioning into flexible polymer networks. We establish a novel label-free, contactless method to measure partition ratio, based on the increase in osmotic pressure induced by external polymer chains partitioning into the network. Moreover, we find a universal law in which the partition constant is solely determined by the squared ratio $(R_g / l_\mathrm{cycle})^2$, where $R_g$ is the gyration radius of the polymer chain and $l_\mathrm{cycle}$ is the characteristic mesh size of the network, as defined by the cycle length.