Enhanced Biogas Production via Anaerobic Co-Digestion of Slaughterhouse and Food Waste Using Ferric Oxide as a Sustainable Conductive Material

TL;DR

This study demonstrates that adding ferric oxide at an optimal dose significantly improves biogas production and waste reduction in anaerobic co-digestion of slaughterhouse wastewater and food waste, with potential for industrial application.

Contribution

It is the first to evaluate ferric oxide as a conductive material in co-digestion of slaughterhouse and food waste, showing enhanced biogas yield and process stability.

Findings

Biogas production increased by 81% at optimal ferric oxide dose.

Ferric oxide improved organic matter removal and methane yield.

Excess ferric oxide inhibits biogas production, indicating a threshold effect.

Abstract

The anaerobic co-digestion of slaughterhouse wastewater and food waste offers a sustainable approach to waste treatment and biogas production. However, limited literature was found on the study of ferric oxide as conductive material in co-digestion of the two substrates. This study evaluates the effect of ferric oxide on biogas yield, organic matter removal, and kinetics of anaerobic co-digestion. Five batch tests were performed: four with varying ferric oxide doses and one control. Results showed that ferric oxide significantly enhanced total solids (TS) and volatile solids (VS) reduction. The reactor with 0.5 g ferric oxide per 800 mL working volume achieved the highest TS and VS reduction, corresponding to the maximum methane yield of 9878.95 L methane per kg volatile solid. At this optimal dosage, biogas production increased by 81 percent compared to the control. However, further increases in ferric oxide above the optimal dosage concentration decreases biogas yield, indicating a threshold beyond which inhibitory effects occur. In addition, at this optimal dosage, reduction in BOD and COD was observed due to enhanced microbial activity. Furthermore, ferric oxide stabilizes anaerobic digestion by mitigating inhibitory compounds and promoting direct interspecies electron transfer, leading to improved methane yield. Kinetic modeling using the Logistic Function accurately predicted methane production trends, demonstrating its potential for industrial-scale application. Overall, the study confirms that ferric oxide at an optimal dose significantly enhance biogas yield and system performance during the anaerobic co-digestion.