Enhanced Performance and Stability of Perovskite Solar Cells with Ag-Cu-Zn Alloy Electrodes

TL;DR

This study enhances perovskite solar cell performance and stability by alloying Ag electrodes with Cu and Zn, resulting in improved efficiency, durability, and corrosion resistance compared to pure Ag electrodes.

Contribution

It introduces phase transition engineering of Ag electrodes via Cu and Zn alloying, significantly improving efficiency and operational stability of perovskite solar cells.

Findings

Ag-Cu-Zn alloy electrodes increase PCE from 18.71% to 19.02%.

Alloyed electrodes sustain operation for 460 hours, outperforming pure Ag.

Alloy electrodes exhibit high corrosion resistance and better adhesion.

Abstract

Though the common metal electrode-based perovskite solar cells have achieved a power conversion efficiency of >25%, they also play a crucial role in accelerating the degradation of the cells. In this study, we investigated phase transition engineering in Ag electrodes via Cu and Zn alloying, transforming from a cubic to a tetragonal phase. These alloyed electrodes are then thermally deposited as back electrodes in perovskite solar cells. We conducted a comprehensive analysis of the pure Ag and Ag-Cu-Zn alloys deposited atop a hole-transport layer for use in Cs0.05(FA0.83MA0.17)0.95Pb(I0.83Br0.17)3-based solar cells. Our findings reveal that solar cells developed with pure Ag electrodes demonstrate a power conversion efficiency (PCE) of 18.71%, characterized by a fill factor (FF) of 74.8%, an open-circuit voltage (VOC) of 1.08 V, and a short-circuit current density (JSC) of 23.17 mA/cm2. Conversely, solar cells fabricated with optimized Ag0.875Cu0.120Zn0.005 electrodes exhibit enhanced performance metrics, with an FF of 72.5%, VOC of 1.12 V, and JSC of 23.39 mA/cm2, culminating in an elevated PCE of 19.02%. Moreover, this electrode demonstrates remarkable durability, sustaining operational integrity for 460 hours for the PSCs stored in the N2 glove box, in contrast to the 320 hours for cells with Ag electrodes. The Ag-Cu-Zn alloys exhibited high resistance to corrosion and good adhesion on the hole-transport material layer compared to a layer of Ag. These advancements may lead to the realization of cost-effective, durable, and efficient solar energy conversion systems.