Optics of Plasmon-Exciton Nanostructures: Theoretical Models and Physical Phenomena in Metal/J-aggregate Systems

TL;DR

This paper reviews the theoretical models and physical phenomena of plasmon-exciton interactions in hybrid metal/J-aggregate nanostructures, highlighting resonance effects, spectral features, and the influence of structural parameters.

Contribution

It provides a comprehensive theoretical analysis of optical spectra in metal/J-aggregate hybrid nanostructures, including regimes of weak to ultrastrong coupling and effects of geometry and material properties.

Findings

Resonance and antiresonance phenomena in optical spectra

Spectral band replication in plexcitonic nanoparticles

Influence of size, anisotropy, and intermediate layers on spectra

Abstract

We review the studies of a wide range of optical phenomena resulting from near-field coupling between excitons and localized surface plasmon-polaritons in hybrid nanostructures. Modern physical approaches and theoretical models reported here for the description of light absorption, scattering, and extinction spectra are appropriate for interpreting physical effects in nanosystems containing metals and various excitonic materials, such as molecular aggregates of organic dyes or inorganic quantum-confined semiconductor structures. Using the example of hybrid nanosystems composed of a metal core and an outer shell of dye J-aggregate, we perform a theoretical analysis of the optical spectra behavior in the regimes of weak, strong, and ultrastrong plasmon--exciton coupling. We consider resonance and antiresonance phenomena induced by the coupling of an exciton with dipole and multipole plasmons, including a pronounced dip in light absorption, as well as the spectral band replication effect of plexcitonic nanoparticles and their dimers. We discuss the significant roles of the size-dependent permittivity of the metal core, the effects of anisotropy and chirality of the excitonic J-aggregate shell, and the influence of an intermediate passive layer on the formation of the optical spectra of bilayer, trilayer, and multilayer nanoparticles. The review outlines the experimental and theoretical results for hybrid nanosystems of various geometrical shapes, sizes, and compositions, broadens our understanding of the physical phenomena caused by the plasmon--exciton coupling, and represents the current state of research in the optics of metalorganic nanostructures.