Path integral spin dynamics with exchange and external field

TL;DR

This paper introduces a path integral-inspired method to compute quantum thermal expectation values in spin systems with exchange interactions and time-dependent magnetic fields, bridging quantum and classical simulations.

Contribution

It generalizes previous formalisms by deriving an effective magnetic field for classical spin dynamics from quantum partition functions, enabling accurate quantum expectation calculations.

Findings

Method accurately reproduces quantum expectation values across temperatures.

Works well for both ferromagnetic and antiferromagnetic couplings.

Outperforms classical models in antiferromagnetic cases.

Abstract

In this work, we propose a path integral-inspired formalism for computing the quantum thermal expectation values of spin systems, when subject to magnetic fields that can be time-dependent and can accommodate the presence of Heisenberg exchange interactions between the spins. This is done by deriving an effective magnetic field from the quantum partition function of the system to use in classical atomistic spin dynamics simulations and generalises the formalism presented in our previous work [Phys. Rev. Research 5, 043075 (2023)]. In special cases where the effective field can be computed exactly we compare our results with exact/numerical diagonalisation methods for both ferromagnetic and antiferromagnetic coupling. We show that our method works well across a large temperature range and can reproduce quantum expectation values for antiferromagnetic coupling which is usually not possible with classical models.