FAUST-XXII. Deuteration in the VLA1623-2417 protostellar hot-corinos, cavities, and streamers

TL;DR

This study investigates deuterium fractionation in the VLA1623-2417 protostellar system using ALMA observations of formaldehyde and its deuterated forms, revealing insights into chemical history and formation processes from prestellar to protostellar stages.

Contribution

It provides detailed spatial analysis of deuteration in a protostellar environment, highlighting inheritance of chemical signatures from prestellar phases.

Findings

Deuteration levels vary across different regions, indicating formation history.

D2CO traces cold, grain-surface chemistry in the envelope and streamers.

Deuterium fractionation is inherited from prestellar stages, mostly unaltered.

Abstract

The study of deuterium fractionation is a valuable tool for reconstructing our chemical history from the early prestellar stages to the formation of planets. In the context of the ALMA Large Programme FAUST, we observed formaldehyde, H$_2$CO, and its singly and doubly deuterated forms, HDCO and D$_2$CO, towards the protostellar cluster VLA1623-2417, on scales of ~ 2000 - 50 au. Formaldehyde probes the inner envelopes of the protostars VLA1623A, B, and W, the rotating cavities opened by the VLA1623A outflow, and several streamers. The HDCO and D$_2$CO emissions are observed towards VLA1623A, in its outflow cavities, and in one of the streamers. We estimate the gas temperature from the HDCO lines: T~ 125 K towards VLA1623A, indicating hot-corino emission, lower temperatures in the outflow cavities (20 - 40 K), and in the streamers ($\le15$ K). The D$_2$CO lines also trace the flattened envelope of VLA1623A, where H$_2$CO and HDCO are fainter. This may be due to D$_2$CO formation on dust grains in the cold prestellar phase, and subsequent photodesorption caused by the enhanced UV flux from two nearby B stars. We inferred the molecular deuteration: [HDCO]/[H$_2$CO] ~ 0.16, ~ 0.07 - 0.13, and ~ 0.3; [D$_2$CO]/[H$_2$CO] ~ 0.003, ~ 0.05 - 0.13, and ~ 0.03 in the hot corino, in the outflow cavities, and in the streamer, respectively. The spatial distribution of D$_2$CO, which points to formation on dust grains, and the similar values of [HDCO]/[H$_2$CO] and [D$_2$CO]/[H$_2$CO] in the components of the system, suggest that deuterium fractionation occurs at the prestellar stage and is then inherited, mostly unaltered, in the protostellar phase.