HCN and C2H2 in the atmosphere of a T8.5+T9 brown dwarf binary

TL;DR

This study presents the first JWST mid-infrared spectrum of a T-dwarf binary, detecting molecules including HCN and C2H2, revealing unexpected atmospheric chemistry and challenging existing models of brown dwarf atmospheres.

Contribution

First JWST/MRS spectrum of a T-dwarf binary with detection of HCN and C2H2, providing new insights into atmospheric chemistry and vertical mixing processes.

Findings

Detection of HCN and C2H2 at high significance levels.

Evidence of intense vertical mixing in the atmosphere.

Challenges to existing atmospheric models for brown dwarfs.

Abstract

T-type brown dwarfs present an opportunity to explore atmospheres teeming with molecules such as H2O, CH4 and NH3, which exhibit a wealth of absorption features in the mid-infrared. With JWST, we can finally explore this chemistry in detail, including for the coldest brown dwarfs that were not yet discovered in the Spitzer era. This allows precise derivations of the molecular abundances, which in turn informs our understanding of vertical transport in these atmospheres and can provide clues about the formation of cold brown dwarfs and exoplanets. This study presents the first JWST/MRS mid-IR spectrum (R ~ 1500-3000) of a T-dwarf: the T8.5+T9 brown dwarf binary WISE J045853.90+643451.9. We fit the spectrum using a parameterized P-T profile and free molecular abundances (i.e., a retrieval analysis), treating the binary as unresolved. We find a good fit with a cloud-free atmosphere and identify H2O, CH4 and NH3 features. Moreover, we make the first detections of HCN and C2H2 (at 13.4$\sigma$ and 9.5$\sigma$ respectively) in any brown dwarf atmosphere. The detection of HCN suggests intense vertical mixing ($K_{zz}\sim10^{11}$cm$^2$s$^{-1}$), challenging previous literature derivations of $K_{zz}$ values for T-type brown dwarfs. Even more surprising is the C2H2 detection, which cannot be explained with existing atmospheric models for isolated objects. This result challenges model assumptions about vertical mixing, and/or our understanding of the C2H2 chemical network, or might hint towards a more complex atmospheric processes such as magnetic fields driving aurorae, or lightning driving ionization. These findings open a new frontier in studying carbon chemistry within brown dwarf atmospheres.