Imaging van Hove Singularity Heterogeneity in Overdoped Graphene

TL;DR

This study investigates the spatial inhomogeneity of van Hove singularity doping in overdoped graphene using advanced microscopy and spectroscopy techniques, revealing local variations caused by Ytterbium intercalation and substitution.

Contribution

It demonstrates the spatial heterogeneity of van Hove singularity doping in graphene and links it to local Yb dopants and intercalation variations, providing insights into doping inhomogeneity effects.

Findings

Significant inhomogeneity in van Hove singularity position in overdoped graphene.

Local Yb dopants cause strong shifts in doping and quasiparticle renormalization.

Theoretical calculations confirm Yb impurities alter local electronic potential.

Abstract

Tuning the chemical potential of a solid to the vicinity of a van Hove singularity (vHS) is a well-established route to discovering emergent quantum phases. In monolayer graphene, the use of electron-donating metal layers has recently emerged as a method to dope the chemical potential to the nearest vHS, as evidenced by Angle-Resolved Photoemission Spectroscopy (ARPES) measurements. In this work, we study the spatial uniformity of the doping from this process using spectroscopic imaging scanning tunneling microscopy (SI-STM). Using molecular beam epitaxy (MBE), we achieve electron doping of graphene on SiC using Ytterbium (Yb-Graphene). We show using in-situ ARPES that the chemical potential is shifted to within 250 meV of the vHS. Using in-situ SI-STM, we establish that there exists significant inhomogeneity in the vHS position in overdoped graphene. We find two separate reasons for this. First, the spatial inhomogeneity of the intercalated Yb leads to local variations in the doping, with a length scale of inhomogeneity set by the screening length of ~ 3 nm. Second, we observe the presence of substitutional Yb dopants in the graphene basal plane. These Yb dopants cause a strong local shift of the doping, along with a renormalization of the quasiparticle amplitude. Theoretical calculations confirm that the Yb impurities effectively change the local potential, thus energetically shifting the position of the van Hove singularity. Our results point to the importance of considering the spatial structure of doping and its inextricable link to electronic structure.