Observation of quantum oscillations, linear magnetoresistance, and crystalline electric field effect in quasi-two-dimensional PrAgBi$_2$

TL;DR

This study investigates PrAgBi$_2$, revealing quantum oscillations, linear magnetoresistance, and crystalline electric field effects, suggesting it hosts Dirac fermions and complex electronic structures in a layered material.

Contribution

The paper provides the first detailed analysis of quantum oscillations, CEF effects, and Dirac fermions in PrAgBi$_2$, combining experimental magnetotransport data with band structure calculations.

Findings

Observation of quantum oscillations with a small effective mass

Linear, unsaturated magnetoresistance up to 1060% at 2 K

Evidence of Dirac fermions near the Fermi level

Abstract

We report the magnetic and magnetotransport properties with electronic band structure calculation of the Bi square net system PrAgBi$_2$. The magnetization and heat capacity data confirm the presence of a crystalline electric field (CEF) effect in PrAgBi$_2$. Analysis of the CEF effect using a multilevel energy scheme reveals that the ground state of PrAgBi$_2$ consists of five singlets and two doublets. The de Haas-van Alphen (dHvA) quantum oscillations data show a single frequency with a very small cyclotron effective mass of approximately 0.11 $m_e$. A nontrivial Berry phase is also observed from the quantum oscillations data. The magnetotransport data shows linear and unsaturated magnetoresistance, reaching up to 1060\% at 2 K and 9 T. Notably, there is a crossover from a weak-field quadratic dependence to a high-field linear dependence in the field-dependent magnetoresistance data. The crossover critical field $B^*$ follows the quadratic temperature dependence, indicating the existence of Dirac fermions. The band structure calculation shows several Dirac-like linear band dispersions near the Fermi level and a Dirac point close to the Fermi level, located at the Brillouin zone boundary. \textit{Ab inito} calculations allowed us to ascribe the observed dHvA oscillation frequency to a particular feature of the Fermi surface. Our study suggests layered PrAgBi$_2$ is a plausible candidate for hosting the CEF effect and Dirac fermion in the Bi square net.