Interfacial chemistry meets magnetism: comparison of $Co/Fe_3O_4$ and $Co/{\alpha}-Fe_2O_3$ epitaxial heterostructures

TL;DR

This study compares the interfacial chemistry and magnetic properties of cobalt/Fe3O4 and cobalt/α-Fe2O3 heterostructures, revealing oxidation, magnetic coupling, and interface-driven magnetic modifications.

Contribution

It provides a detailed microscopic and spectroscopic analysis of cobalt/oxide interfaces, highlighting differences in oxidation and magnetic interactions in two distinct heterostructures.

Findings

Cobalt nanostructures oxidize at interfaces, with thicker oxide layers on hematite.

Interfacial reduction of iron modifies magnetic properties, inducing uncompensated moments.

Magnetic domain structures show ferromagnetic coupling between cobalt and both oxides.

Abstract

The magnetic and chemical structure of metal/oxide interfaces were studied in cobalt/magnetite, $Fe_3O_4$, and cobalt/hematite, ${\alpha}-Fe_2O_3$, epitaxial heterostructures using the comprehensive selection of microscopic and spectroscopic methods. It was observed that the cobalt nanostructures and ultrathin films were oxidized at both interfaces, with a thicker cobalt oxide layer in the system with hematite. The formation of cobalt oxides was accompanied by the interfacial reduction of iron that modified magnetic properties of the iron oxides layers. In particular, uncompensated magnetic moments appear in antiferromagnetic hematite, and the orbital magnetic moment of Co grown on magnetite is significantly enhanced for thicknesses below 1 nm. Synchrotron magnetic microscopy showed a direct correlation in the domain structures of the cobalt/iron oxides: ferromagnetic coupling between cobalt and magnetite and between cobalt and the magnetically modified layer of hematite.