Aggregation of dipolar molecules in SiO$_2$ hybrid organic inorganic films: use of silver nanoparticles as inhibitors of molecular aggregation

TL;DR

This study demonstrates that silver nanoparticles effectively inhibit dipolar molecule aggregation in hybrid SiO₂ films, outperforming traditional organic inhibitors, which is crucial for developing advanced nonlinear optical photonic devices.

Contribution

The paper introduces the use of silver nanoparticles as superior inhibitors of dipolar molecule aggregation in hybrid films, leveraging their high polarizability for improved material performance.

Findings

Silver nanoparticles effectively inhibit dipolar chromophore aggregation.

Nanoparticles outperform organic inhibitors at room temperature.

Size and synthesis method of nanoparticles confirmed by microscopy and spectroscopy.

Abstract

The technological implementation of hybrid organic-inorganic materials in second order nonlinear optical photonic devices depends strongly on the ability of the host matrixes to contain high loads of dipolar molecules without aggregation. Some organic molecules are often used to diminish the attracting interactions between dipolar molecules in such kind of materials, but their efficiency as inhibitors of molecular aggregation is limited by their polarizability. In this work, we report the use of silver nanoparticles as inhibitors of molecular aggregation in hybrid organic-inorganic films doped with dipolar molecules. The large polarizability of the silver nanoparticles makes them ideal moieties for the inhibition of the electrostatic interactions between dipolar nonlinear optical molecules. The average size of the silver nanoparticles in this work was 70.5 nm in diameter, they were synthesized using silver nitrate (AgNO$_3$) as precursor and aminoethylaminopropyltrimethoxysilane as reducing agent. These nanoparticles were immersed in SiO$_2$ hybrid organic-inorganic sol-gel films doped with dipolar chromophores to study their effect as inhibitors of dipolar chromophores aggregation. The presence of the silver nanoparticles in the solid films was confirmed by transmission electronic microscopy and UV-Visible spectroscopy. UV-Visible spectroscopy was also used to monitor the dipolar chromophores aggregation in the SiO$_2$ films. We found that, at room temperature, silver nanoparticles are good inhibiting chromophores aggregation in comparison with the performance of organic inhibitors.