Direct Visualization of an Incommensurate Unidirectional Charge Density Wave in La$_4$Ni$_3$O$_{10}$

TL;DR

This study visualizes an incommensurate unidirectional charge density wave in La$_4$Ni$_3$O$_{10}$ using STM/STS, revealing a CDW gap and providing insights into its electronic structure and relation to superconductivity.

Contribution

It is the first direct real-space visualization of a CDW in La$_4$Ni$_3$O$_{10}$, linking Fermi surface nesting to CDW formation and contrasting electronic correlations with related compounds.

Findings

Detected a CDW gap of approximately 71 meV.

Visualized an incommensurate unidirectional CDW in La$_4$Ni$_3$O$_{10}$.

Suggested CDW as a subsidiary phase of a spin density wave.

Abstract

Superconductivity emerges in both La$_3$Ni$_2$O$_7$ and La$_4$Ni$_3$O$_{10}$ under high pressure by suppressing their density-wave transitions, but critical temperature (Tc) differs significantly between these two compounds. To gain deeper insights into the distinct superconducting states, it is essential to unravel the nature of the density-wave states at ambient pressure, a topic that remains largely unexplored. Here, using scanning tunneling microscopy/spectroscopy (STM/STS), we report the direct visualization of an incommensurate unidirectional charge density wave (CDW) in La$_4$Ni$_3$O$_{10}$ in real space. The density of states (DOS) is strongly depleted near $E_F$, indicating the opening of a CDW gap of $2{\Delta} \approx 71$ meV, which is unfavorable for the formation of superconductivity at ambient pressure. We propose that the CDW arises from Fermi surface nesting, and is likely a subsidiary phase of a spin density wave. Compared to La$_3$Ni$_2$O$_7$, the weaker electronic correlation in La$_4$Ni$_3$O$_{10}$ is likely one reason for the lower $T_c$.