Quantifying the creation of negatively charged boron vacancies in He-ion irradiated hexagonal boron nitride

TL;DR

This study quantifies the creation efficiency of negatively charged boron vacancies in hexagonal boron nitride induced by helium ion irradiation, providing insights for optimizing luminescent quantum defects.

Contribution

It introduces a method to measure the generation rate of negatively charged boron vacancies in hBN using magnetic resonance and a microscopic charge model.

Findings

Lower bound of 0.2% for negatively charged vacancy formation

Quantitative relation between vacancy density and spin splitting

Protocol for assessing vacancy creation efficiency

Abstract

Hexagonal boron nitride (hBN) hosts luminescent defects possessing spin qualities compatible with quantum sensing protocols at room temperature. Vacancies, in particular, are readily obtained via exposure to high-energy ion beams. While the defect creation mechanism via such irradiation is well understood, the occurrence rate of optically active negatively charged vacancies ($V_B^-$) is an open question. In this work, we exploit focused helium ions to systematically generate optically active vacancy defects in hBN flakes at varying density. By comparing the density-dependent spin splitting measured by magnetic resonance to calculations based on a microscopic charge model, in which we introduce a correction term due to a constant background charge, we are able to quantify the number of $V_B^-$ defects generated by the ion irradiation. We find a lower bound for the fraction (0.2%) of all vacancies in the optically active, negatively charged state. Our results provide a protocol for measuring the generation efficiency of $V_B^-$, which is necessary for understanding and optimizing luminescent centers in hBN.