Interaction energies in nematic liquid crystal suspensions

TL;DR

This paper derives an asymptotic expansion for the minimal Dirichlet energy of nematic liquid crystal maps outside particles, revealing Coulomb-like interactions and providing a rigorous estimate of the electrostatics analogy used in physics.

Contribution

It provides the first rigorous derivation of the energy expansion and Coulomb interactions in nematic suspensions, validating the electrostatics analogy.

Findings

Energy expansion includes Coulomb-like interactions

Quantifies error in linearization approximation

Confirms electrostatics analogy in nematic colloids

Abstract

We establish, as $\rho\to 0$, an asymptotic expansion for the minimal Dirichlet energy of $\mathbb S^2$-valued maps outside a finite number of three-dimensional particles of size $\rho$ with fixed centers $x_j\in\mathbb{R}^3$, under general anchoring conditions at the particle boundaries. Up to a scaling factor, this expansion is of the form \begin{align*} E_\rho = \sum_j \mu_j -4\pi\rho \sum_{i\neq j} \frac{\langle v_i,v_j\rangle}{|x_i-x_j|} +o(\rho)\,, \end{align*} where $\mu_j$ is the minimal energy after zooming in at scale $\rho$ around each particle, and $v_j\in\mathbb{R}^3$ is a torque determined by the far-field behavior of the corresponding single-particle minimizer. The above expansion highlights Coulomb-like interactions between the particle centers. This agrees with the \textit{electrostatics analogy} commonly used in the physics literature for colloid interactions in nematic liquid crystal. That analogy was pioneered by Brochard and de Gennes in 1970, based on a formal linearization argument. We obtain here for the first time a precise estimate of the energy error introduced by this linearization procedure.