Numerical Modelling of Buffer Layers for Advancing CZTSSe Solar Cell Efficiency

TL;DR

This paper uses simulations to optimize buffer layers and device parameters in CZTSSe solar cells, achieving over 28% efficiency and analyzing stability factors to enhance sustainable photovoltaic technology.

Contribution

It introduces a systematic simulation-based optimization of buffer layers and device parameters for CZTSSe solar cells, achieving high efficiency and stability insights.

Findings

Achieved 28.38% efficiency with optimized device configuration.

Identified key parameters affecting device performance and stability.

Provided guidelines for practical manufacturing of high-efficiency CZTSSe solar cells.

Abstract

Kesterite is a leading candidate among inorganic thin-film photovoltaic technologies, offering sustainable and environmentally friendly solutions without reliance on critical raw materials. This study investigates the performance of CZTSSe-based kesterite solar cells using SCAPS-1D simulations. Four device configurations are analyzed by integrating the CZTSSe absorber layer with buffer materials, including CdS, SnS2, IGZO, and ZnSe, selected based on their energy band alignment. Moreover, key parameters influencing device efficiency, such as absorber defect density, buffer layer thickness, and the donor and defect densities of the buffer materials, are systematically examined. The thickness of the absorber layer and acceptor density are optimized, considering practical manufacturing constraints. Following optimization, the i-ZnO/SnS2/CZTSSe/Au configuration achieves a notable efficiency of 28.38%, with a VOC of 0.83 V, a JSC of 39.93 mA/cm2, and a fill factor of 85.4%. Furthermore, the stability of the optimized structures is evaluated under varying conditions, including resistances, temperature, generation and recombination dynamics, as well as JV and QE characteristics. These findings provide valuable insights for advancing the efficiency and stability of CZTSSe solar cells, contributing to the development of sustainable photovoltaic technologies.