Phenomenological modeling of the stress-free two-way shape-memory effect in semi-crystalline networks: Formulation, numerical simulation, and experimental validation

TL;DR

This paper develops a phenomenological model for semi-crystalline polymers exhibiting stress-free two-way shape-memory effects, validated through experiments on poly(ε-caprolactone) and analyzed for various influencing factors.

Contribution

It introduces a new one-dimensional continuum model for semi-crystalline polymers with two-way SME, supported by experimental validation and comprehensive analysis.

Findings

Model accurately predicts stress-free two-way SME behavior.

Experimental data confirms the influence of temperature, rates, and phases.

Provides insights for designing shape-memory polymer applications.

Abstract

Polymers exhibiting the stress-free two-way shape-memory effect (SME) represent an appealing solution to achieve self-standing reversible actuation that is a fundamental feature required by numerous applications. The present paper proposes a one-dimensional continuum phenomenological framework to model single-component semi-crystalline polymer networks exhibiting both the one-way SME and the two-way SME under stress and stress-free conditions. A comprehensive experimental campaign is first performed on semi-crystalline networks based on poly($\varepsilon$-caprolactone) (PCL) to characterize the mechanical and thermal properties as well as the one-way and two-way shape memory behavior of the material under different thermo-mechanical conditions. The results guide the formulation of the model, elucidating the selection of the control and phase variables and motivating the choice of their evolution laws. Model capabilities are then demonstrated against experimental data. All the phenomena that influence the stress-free two-way SME, including the actuation temperature, heating/cooling rates, applied stress/strain, and the amount of skeleton and actuation phase, are analyzed and discussed, giving new important insight for application development.