Investigation of coalescence and pinch-off processes of a self-rewetting drop interacting with a liquid layer

TL;DR

This study investigates the coalescence and pinch-off behavior of self-rewetting fluids interacting with a liquid layer under nonuniform heating, revealing earlier pinch-off and the influence of thermocapillary forces compared to normal fluids.

Contribution

It introduces a phase-field lattice Boltzmann model to analyze the unique thermocapillary effects of self-rewetting fluids on drop dynamics under nonuniform heating.

Findings

Self-rewetting fluids undergo earlier pinch-off than normal fluids.

Increasing Ohnesorge number suppresses pinch-off, highlighting viscous effects.

Thermocapillary forces significantly influence coalescence and pinch-off behavior.

Abstract

Self-rewetting fluids (SRFs), such as long-chain aqueous alcohols, are a special class of liquids with surface tension that is anomalously dependent quadratically on temperature, resulting in thermocapillary flows that differ significantly from those in normal fluids (NFs). This study focuses on investigating the behavior of SRF drops interacting with a liquid layer under nonuniform heating conditions. In this regard, we employ a robust central moment-based lattice Boltzmann method with a phase-field model expressed in an axisymmetric formulation to capture three-dimensional effects efficiently. We investigate the coalescence and pinch-off processes in SRFs and compare them to those in NFs. Our simulations reveal that SRFs undergo pinch-off earlier than NFs. We also observe that increasing the Ohnesorge number Oh suppresses the pinch-off process, highlighting the relative role of viscous forces, which is modulated by gravity effects or the Bond number Bo. Furthermore, we explore how varying the dimensionless linear and quadratic sensitivity coefficients of surface tension on temperature, M1 and M2, respectively, and the dimensionless heat flux Q influence the coalescence/pinch-off behavior. Interestingly, contrary to the behavior in NFs, in SRFs increasing M2, or Q reduces the time required to pinch-off and widens the region in the Oh-Bo regime map where pinch-off occurs, when compared to the unheated cases. These differences are shown to be due to the variations in the thermocapillary forces on the interface. Overall, we find that under nonuniform heating, the SRFs enhance the pinch-off process compared to NFs across a wider range of conditions.