Production of linear alkanes via the solid-state hydrogenation of interstellar polyynes

TL;DR

This study demonstrates that solid-state hydrogenation of interstellar polyynes at 10 K can produce fully saturated hydrocarbons, providing insights into astrochemical processes and the formation of complex organic molecules in space.

Contribution

The paper provides the first experimental validation of converting polyynes into saturated hydrocarbons via surface hydrogenation under space-like conditions.

Findings

Confirmed formation of C4H10 and tentative C6H14 from polyynes.

Hydrogenation rates of HCCH and HCCCCH are comparable at 10 K.

Polyynes can be transformed into saturated hydrocarbons in interstellar environments.

Abstract

Highly unsaturated carbon chains, including polyynes, have been detected in many astronomical regions and planetary systems. With the success of the QUIJOTE survey of the TMC-1, the community has seen a "boom" in the number of detected carbon chains. On the other hand, the Rosetta mission revealed the release of fully saturated hydrocarbons, C$_3$H$_8$, C$_4$H$_{10}$, C$_5$H$_{12}$, and (under specific conditions) C$_6$H$_{14}$ with C$_7$H$_{16}$, from the comet 67P/Churyumov-Gerasimenko. The detection of the latter two is attributed to dust-rich events. Similarly, the analysis of samples returned from asteroid Ryugu by Hayabusa2 mission indicates the presence of long saturated aliphatic chains in Ryugu's organic matter. The surface chemistry of unsaturated carbon chains under conditions resembling those of molecular clouds can provide a possible link among these independent observations. However, laboratory-based investigations to validate such a chemistry is still lacking. In the present study, we aim to experimentally verify the formation of fully saturated hydrocarbons by the surface hydrogenation of C$_{2n}$H$_2$ ($n>1$) polyynes under ultra-high vacuum conditions at 10 K. We undertook a two-step experimental technique. First, a thin layer of C$_2$H$_2$ ice was irradiated by UV-photons ($\geq$ 121 nm) to achieve a partial conversion of C$_2$H$_2$ into larger polyynes: C$_4$H$_2$ and C$_6$H$_2$. Afterwards, the obtained photoprocessed ice was exposed to H atoms to verify the formation of various saturated hydrocarbons. In addition to C$_2$H$_6$, which was investigated previously, the formation of larger alkanes, including C$_4$H$_{10}$ and (tentatively) C$_6$H$_{14}$, is confirmed by our study. A qualitative analysis of the obtained kinetic data indicates that hydrogenation of HCCH and HCCCCH triple bonds proceeds at comparable rates, given a surface temperature of 10 K.}