Thermofluidic non-equilibrium assembly of reconfigurable functional structures

TL;DR

This paper demonstrates a novel thermofluidic non-equilibrium assembly method for creating reconfigurable 3D colloidal structures with tunable photonic properties, driven by laser-induced local heating and heat dissipation.

Contribution

It introduces a new thermofluidic assembly technique that enables rapid, ordered, and reconfigurable 3D structures with controllable optical features.

Findings

Structures assembled within minutes.

Structures exhibit tunable photonic stopbands.

Particle fluxes control structure reconfiguration.

Abstract

Non-equilibrium assembly, driven by fluxes controllable by continuous external energy inputs, enables dynamic and reconfigurable structures. Such controlled 3D assembly is desired for the design of adaptive materials that exploit structure-function relationships, but has remained challenging. We present a non-equilibrium assembly of colloidal particles mediated by laser-induced local heating and continuous heat dissipation. These 3D out-of-equilibrium structures, assembled in a matter of a few minutes, were highly ordered and exhibited tunable photonic stopbands. We quantify the particle fluxes from the underlying assembly processes and report the growth dynamics of the assembled structures. Furthermore, we demonstrate the modulation of the photonic stopband achieved by modulating the particle fluxes, highlighting the prospects of such thermofluidic assembly for creating reconfigurable functional structures.