Ultrafast lattice and electron dynamics induced in a PbSe crystal by an intense terahertz pulse

TL;DR

This study investigates how intense terahertz pulses induce ultrafast lattice and electron dynamics in a PbSe crystal, revealing coherent phonon oscillations, Kerr effects, and long-lived optical anisotropy.

Contribution

It demonstrates the resonant excitation of anharmonic phonons and long-lived optical anisotropy in PbSe due to intense terahertz pulses, highlighting new ultrafast lattice-electron interaction phenomena.

Findings

Observation of oscillations at fundamental and harmonic phonon frequencies.

Detection of an almost instantaneous Kerr effect.

Identification of long-lived optical anisotropy with decay > 100 ps.

Abstract

We have studied the ultrafast optical response of a PbSe crystal to an intense picosecond terahertz pulse with a peak electric field strength of up to $\sim$ 500 kV/cm. The reflectivity anisotropy signal contains oscillations at the fundamental frequency of the resonant infrared-active phonon mode as well as its second, third, and fourth harmonics. The effect is ascribed to coherent anharmonic phonons resonantly excited by the strong terahertz field. Pump terahertz pulses also induce an almost instantaneous Kerr effect and a long-lived optical anisotropy of the crystal with a characteristic decay time of $\gtrsim$ 100 ps. We consider lattice distortion and phonon-assisted side valley population as possible origins of this metastable state.