Wall Slip Effects on Parameter Estimation for Integral-Type Viscoelastic Models: Insights from High Density Polyethylene and Thermoplastic Elastomer Melts

TL;DR

This paper investigates how wall slip affects the accuracy of parameter estimation in integral-type viscoelastic models for HDPE and TPE melts, highlighting challenges and strategies for different slip behaviors.

Contribution

It provides new insights into the influence of wall slip on model parameterization and proposes alternative approaches for materials with significant slip, like HDPE.

Findings

Wall slip significantly affects HDPE parameter estimation.

TPE exhibits negligible wall slip, enabling accurate modeling.

Alternative parameterization strategies are effective for slip-prone materials.

Abstract

This study explores the impact of wall slip on parameter estimation for integral-type non-linear viscoelastic models with time-strain separable memory functions, specifically examining high-density polyethylene (HDPE) and thermoplastic elastomer (TPE) melts. Significant wall slip was observed in HDPE under non-linear conditions, complicating the characterization of its damping function using step strain data. In contrast, TPE exhibited negligible wall slip across a wide range of strains and shear rates, facilitating successful parameterization of its damping function using the Wagner-type K-BKZ equation and enabling accurate predictions of various material functions. For HDPE, the study investigated alternative approaches to parameterize the K-BKZ equation, including the use of steady and time-dependent material functions at low deformation rates where wall slip effects are minimal. The findings underscore the challenges of estimating parameters in the presence of wall slip and propose strategies to address these challenges, particularly for materials like HDPE, where pronounced slip complicates traditional rheological characterization.