Growth and inelastic light scattering studies on Sr2Nb2O7 single crystals

TL;DR

This study reports the growth of high-quality Sr2Nb2O7 single crystals and investigates their phonon behavior across a phase transition at approximately 488 K using Raman and Brillouin scattering, revealing significant phonon mode shifts.

Contribution

The paper presents the first detailed inelastic light scattering analysis of Sr2Nb2O7 single crystals across the phase transition, highlighting phonon mode shifts and anomalies associated with the incommensurate phase transition.

Findings

Phonon modes exhibit significant shifts across the phase transition.

A new optical phonon mode appears in the incommensurate phase.

Acoustic phonons show anomalies near the transition temperature.

Abstract

A crack free and high structural quality Sr2Nb2O7 single crystals were grown by the optical float zone method using optimized growth parameters. Laue pattern confirms single crystalline nature of the grown crystal. Temperature dependent Raman and Brillouin light scattering studies reveal a significant shift in phonon modes across normal to incommensurate phase transition (Tn-in) which occurs ~ 488 K. In the temperature range from 900 down to 500 K, two optical phonon modes about 63 (B1 mode) and 54 cm-1 (A1 mode) were observed. The frequency of A1 mode strongly decreases with an increase in temperature above the Tn-in while the frequency of this mode almost remains constant below the Tn-in. In contrast the frequency of B1 phonon mode is found to increase with temperature in the range of 500 - 900 K but it does not display a significant shift below the phase transition temperature. In addition in the incommensurate phase a new optical phonon mode at 35 cm-1 also begins to appear and exhibits strong stiffening behavior with increase in temperature in the range of 300 - 488 K. Moreover, the anomalous behavior of the acoustic phonon across Tn-in were further probed using Brilliouin scattering. Longitudinal acoustic phonon mode at 41 GHz exhibits strong change in slope near Tn-in. In addition, the transverse acoustic modes at 28.6 and 22.4 GHz also exhibit strong anomalies with minimum in frequency near Tn-in. The inelastic light scattering studies provide valuable information on the phase transition.