Highly-stable, eco-friendly and selective Cs2AgBiBr6 perovskite-based ozone sensor

TL;DR

This paper presents a lead-free, eco-friendly Cs2AgBiBr6 perovskite-based sensor capable of room temperature ozone detection with high stability, selectivity, and low energy consumption, addressing toxicity and operational challenges of traditional perovskites.

Contribution

It introduces a novel lead-free double perovskite sensor for ozone detection that operates efficiently at room temperature without harmful solvents or high energy input.

Findings

High ozone sensing stability over time and varying conditions

Exceptional selectivity for ozone over other gases

Effective interaction between ozone and perovskite surface confirmed by calculations

Abstract

Lead halide perovskites have attracted considerable attention as potential gas sensing elements due to their unique ability to detect and respond to an external stimulus with measurable electrical or optical signals. The distinctive characteristics of these materials lie in their ability to operate upon gas exposure at room temperature. However, the presence of lead (Pb) poses a serious challenge for their widespread application and commercialization, owing to its toxicity. To address this issue, lead-free Cs2AgBiBr6 double perovskite is explored as a promising alternative sensing element for room temperature gas detection. This sensor can be regarded as eco-friendly for the following reasons: it does not contain Pb; it is synthesized at room temperature without using strong organic solvents; and it operates and recovers at room temperature without heating or UV irradiation and with a very low input voltage (0.1V), thus reducing overall energy consumption. The influence of the perovskite morphology on the ozone (O3) sensing performance is investigated, as well as the sensing stability under varying conditions of time, humidity, and temperature. Notably, the sensors' exceptional selectivity for O3 over other gases and the interaction between the gases and the perovskite surface is confirmed through experimental and first-principles calculations.