Self-diffusion anomalies of an odd tracer in soft-core media

TL;DR

This paper investigates how odd-diffusive tracers in soft-core media exhibit reversed self-diffusion anomalies at high densities, revealing that oddness can invert the typical diffusion behavior and enhance dynamics.

Contribution

The study introduces a field-theoretic approach to show that oddness in tracers reverses the known diffusion anomaly in soft-core media, supported by Brownian dynamics simulations.

Findings

Odd tracers reverse the GCM self-diffusion anomaly at high densities.

Interactions can enhance the dynamics of odd tracers even in dense systems.

Strong agreement between theory and Brownian dynamics simulations.

Abstract

Odd-diffusive systems, characterised by broken time-reversal and/or parity symmetry, have recently been shown to display counterintuitive features such as interaction-enhanced dynamics in the dilute limit. Here we we extend the investigation to the high-density limit of an odd tracer embedded in a soft-Gaussian core medium (GCM) using a field-theoretic approach based on the Dean-Kawasaki equation. Our theory reveals that interactions can enhance the dynamics of an odd tracer even in dense systems. We demonstrate that oddness results in a complete reversal of the well-known self-diffusion ($D_\mathrm{s}$) anomaly of the GCM. Ordinarily, $D_\mathrm{s}$ exhibits a non-monotonic trend with increasing density, approaching but remaining below the interaction-free diffusion, $D_0$, ($D_\mathrm{s} < D_0$) so that $D_\mathrm{s} \uparrow D_0$ at high densities. In contrast, for an odd tracer, self-diffusion is enhanced ($D_\mathrm{s}> D_0$) and the GCM anomaly is inverted, displaying $D_\mathrm{s} \downarrow D_0$ at high densities. The transition between the standard and reversed GCM anomaly is governed by the tracer's oddness, with a critical oddness value at which the tracer diffuses as a free particle ($D_\mathrm{s} \approx D_0$) across all densities. We validate our theoretical predictions with Brownian dynamics simulations, finding strong agreement between the two.