Magnetic ground state and excitations in mixed 3$d$-4$d$ quasi-1D spin-chain oxide Sr$_3$NiRhO$_6$

TL;DR

This study investigates the magnetic ground state and excitations in the mixed 3d-4d quasi-1D spin-chain oxide Sr3NiRhO6 using muon spin rotation and neutron scattering, revealing long-range order and gapped excitations.

Contribution

It provides the first detailed characterization of the magnetic structure and excitations in Sr3NiRhO6, highlighting its quasi-1D magnetic behavior and the nature of its spin-wave spectrum.

Findings

Long-range magnetic order below 50 K confirmed by μSR.

Gapped quasi-1D magnetic excitations observed via inelastic neutron scattering.

Spin-wave spectrum fitted with ferromagnetic exchange and single ion anisotropy.

Abstract

Entanglement of spin and orbital degrees of freedom, via relativistic spin-orbit coupling, in 4$d$ transition metal oxides can give rise to a variety of novel quantum phases. A previous study of mixed 3$d$-4$d$ quasi-1D spin-chain oxide Sr$_3$NiRhO$_6$ using the magnetization measurements by Mohapatra et al. [Phys. Rev. B 75, 214422 (2007)] revealed a partially disordered antiferromagnetic (PDA) structure below 50 K [Mohapatra et al, Phys. Rev. B 75, 214422 (2007)]. We here report the magnetic ground state and spin-wave excitations in Sr$_3$NiRhO$_6$, using muon spin rotation and relaxation ($\mu$SR), and neutron (elastic and inelastic) scattering techniques. Our neutron diffraction study reveals that in the magnetic structure of Sr$_3$NiRhO$_6$, Rh$^{4+}$ and Ni$^{2+}$ spins are aligned ferromagnetically in a spin-chain, with moments along the crystallographic $c$-axis. However, spin-chains are coupled antiferromanetically in the $ab$-plane. $\mu$SR reveals the presence of oscillations in the asymmetry-time spectra below 50 K, supporting the long-range magnetically ordered ground state. Our inelastic neutron scattering study reveals gapped quasi-1D magnetic excitations with a large ratio of gap to exchange interaction. The observed spin-wave spectrum could be well fitted with a ferromagnetic isotropic exchange model (with $J = 3.7 $ meV) and single ion anisotropy ($D=10$ meV) on the Ni$^{2+}$ site. The magnetic excitations survive up to 85 K, well above the magnetic ordering temperature of $\sim 50$ K, also indicating a quasi-1D nature of the magnetic interactions in Sr$_3$NiRhO$_6$.