Strongly Anisotropic Charge Dynamics in La3Ni2O7 with Coherent-to-Incoherent Crossover of Interlayer Charge Dynamics

TL;DR

This study reveals highly anisotropic charge dynamics in La3Ni2O7, showing a crossover from coherent to incoherent interlayer charge transport with temperature, while in-plane charge transport remains coherent across the studied temperature range.

Contribution

It provides the first detailed optical spectroscopy analysis of charge dynamics anisotropy and the coherent-incoherent crossover in La3Ni2O7.

Findings

Crossover from coherent to incoherent interlayer charge dynamics at higher temperatures.

Persistent coherent in-plane charge transport from 10 K to 300 K.

Strong anisotropy in charge dynamics at low temperatures.

Abstract

We report an optical spectroscopy study of the charge-dynamics anisotropy in the La3Ni2O7 single crystals with the electric field of the incident light parallel to the crystalline c-axis and ab-plane respectively. The evolution of the low-energy part of its c-axis optical conductivity spectra ({\sigma}1c({\omega})) from a Drude component to a finite-energy peak, together with the change in the c-axis electron mean-free-path which is distinctly longer than the c-axis lattice constant at 10 K but is shorter than the c-axis lattice constant at 300 K, demonstrates a crossover from coherent to incoherent interlayer charge dynamics in La3Ni2O7, which is associated with the variation from weak to strong dissipation within its ab-plane. In contrast, the Drude component robust in its {\sigma}1ab({\omega}) and the long ab-plane electron mean-free-path greater than the a-axis and b-axis unit-cell lengths manifest the persistence of coherent in-plane charge dynamics from 10 to 300 K. Thus, the charge dynamics in La3Ni2O7 shows a remarkable anisotropy at high temperatures. At low temperatures, the large values of the ratio between the ab-plane and c-axis Drude weights and the ratio {\sigma}1ab({\omega} -> 0)/{\sigma}1c({\omega} -> 0) indicate a strong anisotropy of the low-temperature charge dynamics in La3Ni2O7.