3D Printable Plasmonic Titanium Nitride Nanoparticles Enhanced Thermoplastic Polyurethane Composite for Improved Photothermal De-Icing and Infrared Labeling

TL;DR

This study develops a 3D printable titanium nitride/thermoplastic polyurethane composite filament with enhanced photothermal properties for applications like de-icing and infrared labeling, supported by experimental and simulation analyses.

Contribution

It introduces a novel TiN-TPU composite filament for 3D printing with superior photothermal and mechanical performance, combining synthesis, experimental testing, and simulation.

Findings

Printed patterns show ~2.5°C temperature increase under IR LED light.

T-TPU exhibits improved mechanical properties over neat TPU.

Finite element simulations confirm enhanced photothermal response.

Abstract

Plasmonic nanomaterials offer a direct and effective approach to harnessing solar energy. Specifically, plasmonic semiconductors enable a highly efficient light-to-heat conversion process, outperforming noble metals in stability, cost-effectiveness, and accessibility. In this study, a composite 3D printing filament (T-TPU), composed of titanium nitride (TiN) and thermoplastic polyurethane (TPU), was synthesized using a combined extrusion process involving a twin-screw extruder and a single-screw extruder. The resulting T-TPU filament could be used with fused deposition modeling (FDM) 3D printing to produce custom-designed patterns. Notably, these printed patterns exhibited superior photothermal performance, with potential applications in photothermal de-icing and infrared labeling. Additionally, the wavelength-dependent plasmonic and photothermal responses of the printed patterns were experimentally investigated and supported by finite elemental method (FEM) simulations, revealing a temperature increase of approximately 2.5 under IR LED light when compared to commercial black thermoplastic polyurethane (C-TPU), that was more obvious than a difference less than 1 under UV or visible LED light sources. Finally, the mechanical properties of T-TPU, altered by the inclusion of TiN nanoparticles, were assessed, showing a slight enhancement in modulus and friction coefficient relative to neat TPU (N-TPU). Molecular dynamics (MD) simulations indicated that the TiN nanoparticles promoted strong interactions between polymer chains and TiN particles, enhancing the modulus of elasticity and contributing to the improved mechanical properties of T-TPU. These findings suggest improved abrasion resistance, demonstrating the stability and durability of the composite material.