Realistic ab initio predictions of excimer behavior under collective light-matter strong coupling

TL;DR

This paper introduces an ab initio quantum electrodynamics coupled cluster method to study how collective strong light-matter coupling influences excimer behavior, revealing a critical transition that inhibits excimer formation.

Contribution

The paper develops a novel ab initio model for collective strong coupling, enabling detailed analysis of excimer potential energy surfaces and vibrational states under realistic light-matter interactions.

Findings

Collective strong coupling causes an abrupt transition in excimer vibrational landscape.

Beyond a critical coupling, excimer formation is inhibited.

The model accurately describes electronic and electron-photon correlations.

Abstract

Experiments show that light-matter strong coupling affects chemical properties, though the underlying mechanism remains unclear. We present an ab initio quantum electrodynamics coupled cluster method for the collective strong coupling regime. The model accurately describes electronic and electron-photon correlation within a molecular subsystem, while a simplified description of the collective polaritonic excitations allows for realistic microscopic light-matter couplings. We illustrate the model by investigating the potential energy surfaces of the argon dimer. This provides a prototype for excimers, and we analyze the ground and excited state vibrational levels. In the collective regime (small light-matter coupling, large number of molecules), the ground state potential energy surface and the first vibrational levels of the excited state are not changed significantly. However, collective strong coupling produces an abrupt transition in the vibrational landscape of the excimer, causing higher levels to behave similarly to ground state vibrations. Beyond a critical collective coupling strength, the excimer formation is thus inhibited.