Fractal structure, depinning, and hysteresis of dislocations in high-entropy alloys

TL;DR

This paper studies the complex fractal structures and hysteresis behavior of dislocations in high-entropy alloys, revealing temperature-dependent changes in dislocation geometry and pinning effects due to chemical heterogeneity.

Contribution

It introduces a novel analysis of dislocation structures in HEAs using spatial correlation functions and models their pinning and hysteresis phenomena.

Findings

Dislocations exhibit fractal geometry with a Hurst exponent of 1/2 at high temperature.

At low temperature, dislocation structures become more correlated with larger Hurst exponents.

Hysteresis and pinning emerge at low temperature due to local lattice distortions.

Abstract

High-entropy alloys (HEAs) are complex alloys containing multiple elements in high concentrations. Plasticity in HEAs is carried by dislocations, but the random nature of their composition pins dislocations, effectively hindering their motion. We investigate the resulting complex structure of the dislocation in terms of spatial correlation functions, which allow us to draw conclusions on the fractal geometry of the dislocation. At high temperature, where thermal fluctuations dominate, dislocations adopt the structure of a random walk with Hurst exponent $1/2$ or fractal dimension $3/2$. At low temperature we find larger Hurst exponents (lower dimensions), with a crossover to an uncorrelated structure beyond a correlation length. These changes in structure are accompanied by an emergence of hysteresis (and hence pinning) in the motion of the dislocation at low temperature. We use a modified Labusch/Edwards-Wilkinson-model to argue that this correlation length must be an intrinsic property of the HEA. This means dislocations in HEAs are an individual pinning limit, where segments of the dislocation are independently pinned by local distortions of the crystal lattice that are induced by chemical heterogeneity.