Structure, dynamics and phase transitions in electric field assembled colloidal crystals and glasses

TL;DR

This paper explores how AC electric fields influence the assembly, structure, and phase transitions of colloidal particles, revealing complex behaviors and mechanisms relevant for reconfigurable materials and micro-robotics.

Contribution

It provides new insights into the effects of particle size, zeta potential, voltage, and frequency on colloidal assembly and phase transitions under AC electric fields.

Findings

Frequency-driven disorder-order-disorder phase transition identified

Dynamics of diffusion and active motion characterized

Formation of both crystalline and glassy structures observed

Abstract

Field-induced assembly of colloidal particles into structures of desired configurations is extremely relevant from the viewpoint of producing field-assembled micro-swimmers and reconfigurable smart materials. However, the behaviour of colloidal particles under the influence of alternating current (AC) electric fields remains a topic of ongoing investigation due to the complex effects of various control parameters. Here we examine the role of several factors including particle size, zeta potential, voltage and frequency of the applied field in the formation of different structural configurations ranging from crystals to glasses, and observe interesting and unexpected behaviours in the structure formation. Additionally, we investigate the dynamics of structure formation; the nature of diffusion and active motion in these out-of-equilibrium systems, and show how that leads to the formation of close-packed or open structures. Lastly, we investigate the frequency-driven disorder-order-disorder phase transition in colloidal crystals, which is a starting point for building reconfigurable systems. Our findings contribute to a deeper understanding of the significant roles of various factors in electric field-induced assembly of colloidal particles, as well as pave the way for potential applications in micro-robotics and next-generation materials.