Pressure effect on the formation kinetics of ferroelectric domain structure uner first order phase transitions

TL;DR

This study investigates how hydrostatic pressure influences the formation and evolution of ferroelectric domain structures during first order phase transitions, revealing pressure-dependent kinetics and stability of domain configurations.

Contribution

It introduces a theoretical analysis of pressure effects on ferroelectric domain kinetics within Landau-Ginzburg framework, highlighting pressure-induced changes in domain formation and stability.

Findings

Pressure increases the tendency for stable polydomain formation.

Domain ordering can occur directly or via metastable phases.

System evolution time is inversely proportional to pressure.

Abstract

Within the framework of Landau-Ginzburg theory the kinetics of domain structure formation in ferroelectrics that undergo first order phase transition was investigated under the influence of hydrostatic pressure. It was established that mechanical action increases the tendency of nonequilibrium system to the formation of stable polydomain structure. Numerical analysis showed that the process of domain ordering can proceed both directly and with formation of short-living metastable polydomain phase. It was found that the incubation period of domain structure formation can be observed at the initial stage of relaxation. Using the KNO3 crystal as an example, it was shown that the time of evolution of the system to the thermodynamic equilibrium is inversely proportional to the pressure value. It was established that in KDP crystals near phase transition point (TC-T<10K) the hydrostatic pressure induces the destruction of ferroelectric ordering. It was shown that the value of critical pressure pcr increases with the growth of quenching temperature.