High sensitivity pressure and temperature quantum sensing in organic crystals

TL;DR

This paper introduces a molecular platform using doped para-terphenyl crystals for highly sensitive pressure and temperature sensing via optically detected magnetic resonance, outperforming diamond-based sensors significantly.

Contribution

The work demonstrates a novel organic crystal-based quantum sensor with enhanced sensitivity and practical advantages over existing diamond NV center sensors.

Findings

Achieved over 85-fold improvement in pressure sensitivity.

Demonstrated measurable molecular orbital shifts due to P and T changes.

Provided a scalable, low-cost platform for quantum sensing applications.

Abstract

The inherent sensitivity of quantum sensors to their physical environment can make them good reporters of parameters such as temperature, pressure, strain, and electric fields. Here, we present a molecular platform for pressure (P) and temperature (T) sensing using para-terphenyl crystals doped with pentacene. We leverage the optically detected magnetic resonance (ODMR) of the photoexcited triplet electron in the pentacene molecule, that serves as a sensitive probe for lattice changes in the host para-terphenyl due to pressure or temperature variations. We observe maximal ODMR frequency variations of df/dP=1.8 MHz/bar and df/dT=247 kHz/K, which are over 1,200 times and three times greater, respectively, than those seen in nitrogen-vacancy centers in diamond. This results in a >85-fold improvement in pressure sensitivity over best previously reported. The larger variation reflects the weaker nature of the para-terphenyl lattice, with first-principles DFT calculations indicating that even picometer-level shifts in the molecular orbitals due to P, T changes are measurable. The platform offers additional advantages including high levels of sensor doping, narrow ODMR linewidths and high contrasts, and ease of deployment, leveraging the ability for large single crystals at low cost. Overall, this work paves the way for low-cost, optically-interrogated pressure and temperature sensors and lays the foundation for even more versatile sensors enabled by synthetic tunability in designer molecular systems.