Chiral, Topological, and Knotted Colloids in Liquid Crystals

TL;DR

This paper reviews how the shape, symmetry, and topology of colloidal particles in liquid crystals influence their physical behavior, defect structures, and potential for creating novel self-assembled materials with complex topologies.

Contribution

It highlights the interplay of topology, symmetry, and nematic order in colloids, revealing new physical phenomena and potential for topology-driven self-assembly in soft matter.

Findings

Topologically nontrivial colloids induce complex defect structures.

Electric fields and laser tweezing can transform director configurations.

Knots and links in defects arise from nonpolar nematic fields.

Abstract

The geometric shape, symmetry, and topology of colloidal particles often allow for controlling colloidal phase behavior and physical properties of these soft matter systems. In liquid crystalline dispersions, colloidal particles with low symmetry and nontrivial topology of surface confine-ment are of particular interest, including surfaces shaped as handlebodies, spirals, knots, mul-ti-component links, and so on. These types of colloidal surfaces induce topologically nontrivial three-dimensional director field configurations and topological defects. Director switching by electric fields, laser tweezing of defects, and local photo-thermal melting of the liquid crystal host medium promote transformations among many stable and metastable particle-induced director configurations that can be revealed by means of direct label-free three-dimensional nonlinear op-tical imaging. The interplay between topologies of colloidal surfaces, director fields, and defects is found to show a number of unexpected features, such as knotting and linking of line defects, often uniquely arising from the nonpolar nature of the nematic director field. This review article high-lights fascinating examples of new physical behavior arising from the interplay of nematic mo-lecular order and both chiral symmetry and topology of colloidal inclusions within the nematic host. Furthermore, the article concludes with a brief discussion of how these findings may lay the groundwork for new types of topology-dictated self-assembly in soft condensed matter leading to novel mesostructured composite materials, as well as for experimental insights into the pure-math aspects of low-dimensional topology.