The interplay between topography and contact line pinning mechanisms on flat and superhydrophobic surfaces

TL;DR

This paper develops a unified model for contact line pinning forces on flat and superhydrophobic surfaces, integrating mechanisms and validated by experiments, aiding in surface design and understanding of wetting behavior.

Contribution

It introduces a general model based on two pinning mechanisms that describes contact line pinning on both flat and microstructured surfaces, bridging a key knowledge gap.

Findings

A general model accurately describes pinning forces on different surfaces.

Experimental validation shows the model's applicability to various surface types.

The framework helps distinguish defect contributions from molecular re-orientation effects.

Abstract

Wettability of a surface depends on both surface chemistry and topography. To move a three-phase contact line, a de-pinning force needs to be applied, which is of practical importance in various applications. However, a unified understanding and description of the de-pinning force on both flat and superhydrophobic surfaces is still lacking. This study aims to bridge the existing gap in our understanding of the three-phase contact line pinning on flat and microstructured superhydrophobic surfaces. The findings indicate that a general model, based on two different pinning mechanisms, can describe the pinning force on both flat and microstructured surfaces. We compare the general model against experimental data from literature, as well as our experiments on flat and microstructured surfaces coated with a liquid-like layer of grafted polymer chains. While this theoretical framework can be useful for designing micro-engineered surfaces on which the contact line behaviour is important, it also provides a potential experimental strategy to distinguish the contribution of defects from that of molecular re-orientation to contact line pinning on a given solid material.