Growth and Spectroscopy of Lanthanide Doped Y$_2$SiO$_5$ Microcrystals for Quantum Information Processing

TL;DR

This study explores the synthesis, growth, and spectroscopic properties of lanthanide-doped Y$_2$SiO$_5$ microcrystals, demonstrating their high optical quality and potential for quantum information applications.

Contribution

It introduces a sol-gel synthesis method for high-quality microcrystals with detailed spectroscopic analysis of doped lanthanides at cryogenic temperatures.

Findings

Sol-gel method produces high-quality microcrystals.

Doped microcrystals exhibit narrow inhomogeneous linewidths.

Optical properties comparable to bulk crystals.

Abstract

Lanthanide-doped Y$_{2}$SiO$_{5}$ microcrystals were prepared using the solution combustion, solid state and sol-gel synthesis techniques. Of these, the sol-gel method yields the most reliable and high-quality X2 phase Y$_{2}$SiO$_{5}$ microcrystals. Absorption and laser site-selective fluorescence measurements of Nd$^{3+}$, Eu$^{3+}$ and Er$^{3+}$ doped material, performed at cryogenic temperatures, indicate that the as-grown microcrystals are of high optical quality with inhomogeneously broadened optical linewidths that are comparable to bulk crystals at similar dopant concentrations.