The Background Interstellar Medium as Observed from Off-Order Low-Resolution Spitzer-IRS Spectra

TL;DR

This study analyzes Spitzer-IRS spectra of the background interstellar medium to investigate PAH molecules, their correlation with dust extinction, and their structural and ionization properties, revealing diverse PAH behaviors across different dust environments.

Contribution

It provides a large catalog of background spectra, detailed analysis of PAH features, and insights into PAH evolution and structure in diffuse interstellar environments.

Findings

Positive correlation between WISE12, E(B-V), and 11.2 μm PAH band.

Identification of three dust temperature regimes affecting PAH emission.

Evidence of PAH structural and ionization changes with environment.

Abstract

Spitzer 'hidden' observations of the background are used to construct a catalog of 4,090 spectra and examine the signature of polycyclic aromatic hydrocarbon (PAH) molecules and their connection to extinction by dust. A strong positive correlation is recovered between WISE12, E(B-V), and the 11.2 $\mu$m PAH band. For 0.06 $\leq$ E(B-V) $\leq$ 5.0, correlations of the 6.2, 11.2, and 12.7 $\mu$m PAH band are positive with E(B-V). Three dust temperature regimes are revealed. Correlations with WISE12 are well-constrained and that with 12.7/11.2 is flat. Decomposition with the NASA Ames PAH IR Spectroscopic Database reveals a tentative positive correlation between the 6.2/11.2 and the PAH ionization fraction, while that with 12.7/11.2 is slightly negative, suggesting PAH structural changes. The relation with PAH size and 6.2/11.2 is negative, while that with 12.7/11.2 is positive. Averaging spectra into five E(B-V) and three T$_{\rm dust}$ bins shows an evolution in PAH emission and variations in 12.7/11.2. Database-fits show an increase in $f_{\rm i}$ and the PAH ionization parameter $\gamma$, but a more stable large PAH fraction. While the largest $\gamma$s are associated with the highest T$_{\rm dust}$, there is no one-to-one correlation. The analysis is hampered by low-quality data at short wavelengths. There are indications that PAHs in the more-diffuse backgrounds behave differently from those in the general interstellar medium. However, they are often still associated with larger scale filamentary cloud-like structures. The spectra and auxiliary data have been made available through the Ames Background Interstellar Medium Spectral Catalog and may guide JWST programs.