Domain wall reactions in multiple-order parameter ferroelectrics

TL;DR

This paper introduces the concept of domain wall reactions in multiple-order-parameter ferroelectrics, revealing how these reactions influence switching dynamics and can be harnessed for defect engineering.

Contribution

It presents the novel idea of domain wall reactions during switching in multiple-order-parameter ferroelectrics, expanding the understanding of ferroelectric behavior beyond traditional models.

Findings

Multiple domain wall types coexist and react during switching.

Domain wall reactions facilitate switching by forming remanent nuclei and defect sites.

The concept applies broadly to all multiple-order-parameter ferroelectrics.

Abstract

The motion of domain walls is crucial for ferroelectric switching. Conventionally, the switching dynamics is believed to be determined by the motion of one or a few low-energy domain wall types of dominant population. Here, we challenge this conventional idea in multiple-order-parameter ferroelectrics. Using hafnia as example, we show that multiple-order-parameter nature not only provides various mobile domain walls and defect-like immobile domain walls, but also enables the domain wall reactions. In analogy with chemical reactions where substances react to form new substances, domain walls could also react to form other domain walls during switching. We identify several elementary domain wall reaction types including synthesis, decomposition, and exchange reactions. Domain walls are continually changed by these reactions during switching so that the switching behavior reflects the statistical average of many domain wall types with distinct mobility and stability. These reactions also lead to phenomenon like remanent nuclei and defect site nucleation that facilitate switching and lower coercive field. Finally, the concept of domain wall reaction is not limited to hafnia but can be generalized to any multiple-order-parameter ferroelectric. This work conceptualizes domain wall reaction, expands theory of ferroelectric switching, and suggests a practical way for defect engineering to control switching behavior.