Doppler-free selective reflection spectroscopy of electric-quadrupole transitions

TL;DR

This paper demonstrates a Doppler-free selective reflection spectroscopy method for electric-quadrupole transitions in cesium vapor, enabling high-resolution measurements and paving the way for studying atom-surface interactions.

Contribution

The study introduces a novel Doppler-free spectroscopy technique for electric-quadrupole transitions, overcoming small signal challenges and enabling precise surface interaction measurements.

Findings

Resolved narrow sub-Doppler lines for forbidden transitions

Measured collisional broadening of electric-quadrupole line

Evidence of cesium-sapphire surface interaction

Abstract

Electric-dipole-forbidden transitions play an important role as in quantum sensing, quantum information, and fundamental test in physics. As such, the development of novel and sensitive spectroscopic methods is of major interest. Here, we present a Doppler-free selective reflection experiment on the 6S1/2 --> 5D5/2 electric-quadrupole transition of cesium vapor at the vicinity of a sapphire window. This is achieved by a precision experiment overcoming limitations due to the small signal amplitude of forbidden transitions. Narrow sub-Doppler lines allow for a collisional broadening measurement on the electric-quadrupole line. The interaction of cesium atoms with the sapphire surface of the cell is evidenced, but, due to its weak contribution, a quantitative analysis remains challenging. Nevertheless, our experiment paves the way for further studies of the Casimir-Polder interaction between exotic excited-state atoms and dielectric surfaces.