Anionic disorder and its impact on the surface electronic structure of oxynitride photoactive semiconductors

TL;DR

This study investigates how anionic disorder in BaTaO$_x$N$_y$ oxynitride semiconductors affects their surface electronic structure and performance in solar-driven water splitting, combining experiments and modeling.

Contribution

It systematically links anionic stoichiometry and surface composition to electronic structure and photoelectrochemical performance of oxynitride photoanodes.

Findings

Anionic composition varies from bulk to surface affecting electronic properties.

Surface layers show downward band bending and reduced semiconducting behavior.

Guidelines for engineering more efficient oxynitride-based photoelectrodes.

Abstract

The conversion of solar energy into chemical energy, stored in the form of hydrogen, bears enormous potential as a sustainable fuel for powering emerging technologies. Photoactive oxynitrides are promising materials for splitting water into molecular oxygen and hydrogen. However, one of the issues limiting widespread commercial use of oxynitrides is the degradation during operation. While recent studies have shown the loss of nitrogen, its relation to the reduced efficiency has not been directly and systematically addressed with experiments. In this study, we demonstrate the impact of the anionic stoichiometry of BaTaO$_x$N$_y$ on its electronic structure and functional properties. Through experimental ion scattering, electron microscopy, and photoelectron spectroscopy investigations, we determine the anionic composition ranging from the bulk towards the surface of BaTaO$_x$N$_y$ thin films. This further serves as input for band structure computations modeling the substitutional disorder of the anion sites. Combining our experimental and computational approaches, we reveal the depth-dependent elemental composition of oxynitride films, resulting in downward band bending and the loss of semiconducting character towards the surface. Extending beyond idealized systems, we demonstrate the relation between the electronic properties of real oxynitride photoanodes and their performance, providing guidelines for engineering highly efficient photoelectrodes and photocatalysts for clean hydrogen production.