Disordered Microporous Sandia Octahedral Molecular Sieves are Tolerant to Neutron Radiation

TL;DR

This study presents the synthesis of microporous Sandia Octahedral Molecular Sieves (SOMS) nanorods that demonstrate high tolerance to neutron radiation and elevated temperatures, making them promising for nuclear applications.

Contribution

The paper introduces a low-temperature solvothermal synthesis method for creating defected microporous Na2Nb2O6 H2O nanorods with demonstrated radiation resistance and thermal stability.

Findings

Nanorods have an average diameter of ~50 nm and length >1 μm.

Post-irradiation, nanorods retain phase, crystallinity, and dimensions.

SOMS nanorods show resistance to radiation-induced amorphization.

Abstract

Materials that possess a porous and defected structure can have a range of useful properties that are sought after, which include their tolerance to nuclear radiation, ability to efficiently store and release isotopes, to immobilize nuclear waste, and to exhibit phase stability even at elevated temperatures. Since nanoscale pores and surface structures can serve as sinks for radiation-induced amorphization, one dimensional (1D) porous nanorods due to their high surface-to-volume ratio have the potential for use as advanced materials in nuclear science applications. In this study, we demonstrate a synthesis and a detailed analysis of microporous 1D octahedral molecular sieves of disodium diniobate hydrate (Na2Nb2O6 H2O) or Sandia Octahedral Molecular Sieves (SOMS). In addition, the stability of these SOMS is evaluated following their exposure to elevated temperatures and neutron irradiation. A surfactant-assisted solvothermal method is used to prepare these SOMS-based nanorods. This relatively low temperature, solution-phase approach can form crystalline nanorods of microporous Na2Nb2O6 H2O. These 1D structures had an average diameter of approximately 50 nm and lengths greater than 1 micrometer. The nanorods adopted a defected microporous phase, which also exhibited a resistance to radiation induced amorphization. The dimensions, phase, and crystallinity of the SOMS-based nanorods after exposure to a high incident flux of neutrons were comparable to those of the as-synthesized products. The radiation tolerance of these microporous SOMS could be useful in the design of materials for nuclear reactors, resilient nuclear fuels, thermally resilient materials, high temperature catalysts, and durable materials for the handling and storage of radioactive waste.