Why heterogeneous cloud particles matter: Iron-bearing species and cloud particle morphology affects exoplanet transmission spectra

TL;DR

This study investigates how different models of heterogeneous cloud particles, especially those containing iron and carbon, influence the optical properties and transmission spectra of exoplanet atmospheres, highlighting the importance of particle morphology assumptions.

Contribution

It compares seven mixing treatments for cloud particle opacities, revealing how assumptions about particle morphology affect spectral features in exoplanet transmission spectra.

Findings

Materials with high refractive indices significantly impact optical properties even at low volume fractions.

Core-shell and homogeneous models better preserve molecular spectral features than effective medium theories.

Different mixing treatments produce observable differences in predicted transmission spectra.

Abstract

The possibility of observing spectral features in exoplanet atmospheres with space missions like JWST and ARIEL necessitates the accurate modelling of cloud particle opacities. In exoplanet atmospheres, cloud particles can be made from multiple materials and be considerably chemically heterogeneous. Therefore, assumptions on the morphology of cloud particles are required to calculate their opacities. The aim of this work is to analyse how different approaches to calculate the opacities of heterogeneous cloud particles affect cloud particle optical properties. We calculate cloud particle optical properties using seven different mixing treatments: four effective medium theories (EMTs: Bruggeman, Landau-Lifshitz-Looyenga (LLL), Maxwell-Garnett, and Linear), core-shell, and two homogeneous cloud particle approximations. We study the mixing behaviour of 21 commonly considered cloud particle materials for exoplanets. To analyse the impact on observations, we study the transmission spectra of HATS-6b, WASP-39b, WASP-76b, and WASP-107b.Materials with large refractive indices, like iron-bearing species or carbon, can change the optical properties of cloud particles when they comprise less than 1\% of the total particle volume. The mixing treatment of heterogeneous cloud particles also has an observable effect on transmission spectroscopy. Assuming core-shell or homogeneous cloud particles results in less muting of molecular features and retains the cloud spectral features of the individual cloud particle materials. The predicted transit depth for core-shell and homogeneous cloud particle materials are similar for all planets used in this work. If EMTs are used, cloud spectral features are broader and cloud spectral features of the individual cloud particle materials are not retained. Using LLL leads to less molecular features in transmission spectra compared to Bruggeman.