Early-time wetting kinetics in surface-directed spinodal decomposition for off-critical quenches: A molecular dynamics study

TL;DR

This molecular dynamics study investigates how composition ratio influences early-time wetting kinetics in surface-directed spinodal decomposition of binary fluids, revealing power-law growth behaviors dependent on surface potential strength and composition.

Contribution

It provides new insights into the composition-dependent wetting kinetics and confirms the potential-dependent growth laws through molecular dynamics simulations.

Findings

Majority wetting layer grows as a power-law with exponent 1/(n+2).

Minority wetting layer exhibits a slower growth exponent, less than 1/(n+2).

Reducing surface potential strength recovers the expected exponent in minority cases.

Abstract

We present results from the molecular dynamics (MD) simulation of surface-directed spinodal decomposition (SDSD) in binary fluid mixtures ($A+B$) with off-critical compositions. The aim is to elucidate the role of composition ratio in the early-time wetting kinetics under the influence of long-range surface potential. In our simulations, the attractive part of surface potential varies as $V(z)= -\epsilon_a/z^{n}$, with $\epsilon_{a}$ being the surface-potential strength. The surface prefers `$A$' species to form the wetting layer. Its thickness [$R_1(t)$] for the majority wetting (number of $A$-type particles [$N_A$] > number of $B$-type particles [$N_B$]), grows as a power-law with an exponent $1/(n+2)$. This is consistent with the early-time kinetics in the form of potential-dependent growth present in the Puri-Binder model. However, for minority wetting ($N_A$ < $N_B$), the growth exponent in $R_1(t)$ is less than $1/(n+2)$. Furthermore, on decreasing the field strength $\epsilon_{a}$, we recover $1/(n+2)$ for a minority wetting case. We provide phenomenological arguments to explain the early-time wetting kinetics for both cases.