Competition between Kondo Effect and RKKY Coupling

TL;DR

This paper reviews the complex interplay between Kondo screening and RKKY interactions in various materials, emphasizing disorder effects, phase diagrams, and recent theoretical advances in understanding magnetic impurity systems.

Contribution

It provides a comprehensive review of the competition between Kondo effect and RKKY coupling, including recent theoretical developments and the impact of disorder and localization.

Findings

Disorder leads to a distribution of Kondo temperatures and RKKY couplings.

Localization transitions significantly affect magnetic interactions.

The competition's complexity increases with impurity concentration and disorder.

Abstract

When magnetic moments are immersed into the Fermi sea of itinerant electrons, rich quantum physics emerges. This is relevant for a wide range of materials including heavy Fermion systems, high temperature superconductors like the cuprates, but also good metals with magnetic impurities, doped semiconductors like Si:P close to the metal-insulator transition, 2D materials like graphene and topological insulators. While each material has its specific properties, requiring detailed modelling, their electronic properties are to some degree governed by the competition between Kondo screening and indirect exchange couplings. In these lecture notes we give an introduction, starting with a review of formation of magnetic moments, the theory of the Kondo effect for a single magnetic impurity in a metal host and the derivation of RKKY coupling between magnetic impurities in a metal host. We review the Doniach diagram and Kondo lattice physics and give an introduction to a self consistent renormalization group theory, taking into account Kondo effect and RKKY coupling between magnetic impurities and review results obtained thereby. We review the effect of gaps and pseudo gaps on Kondo effect and RKKY couplings, and on their competition. Especially for dilute concentration of magnetic moments, disorder effects from randomly distributed impurities result in a distribution of both Kondo temperatures and RKKY couplings. Then, their competition becomes an even more complex problem. Moreover, disorder induced Anderson localization transitions may occur, affecting both Kondo effect and RKKY coupling severely, and changing their competition. These disorder effects on the spin competition are introduced and recent results are reviewed. We conclude with an outlook and list of, in our view, most pressing and interesting open problems.